While A* uses a priority queue, BFS utilizes a queue. Usually, queues are much faster than priority queues (eg. Dequeue() is O(1) vs O(log n)). The benefit of A* is that it normally expands far fewer nodes than BFS, but if that isn't the case, BFS will be faster. That can occur if the heuristic used is poor, or if the graph is very sparse or small, or if the heuristic fails for a given graph.
BFS is particularly useful for unweighted graphs. If the graph is weighted, you need to use Dijkstra's Algorithm. This algorithm applies a priority queue, and as such should rarely be faster than A*, except in cases where the heuristic fails.
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