You can use the assign() function to assign a value to a name in an environment.
According to R Documentation:
Usage
assign(x, value, pos = -1, envir = as.environment(pos),
inherits = FALSE, immediate = TRUE)
Arguments
x
A variable name, given as a character string. No coercion is done, and the first element of a character vector of length greater than one will be used, with a warning.
value
A value to be assigned to x.
pos
Where to do the assignment. By default, assigns into the current environment.
envir
The environment to use.
inherits
Should the enclosing frames of the environment be inspected?
immediate
An ignored compatibility feature.
In your case:
assign(paste("perf.a", "1", sep=""),5)
perf.a1
[1] 5