In order to obtain all different values in a Dataframe you can use distinct. As by the documentation it is stated that method returns another DataFrame.
def
distinct(): DataFrame
Returns a new DataFrame that contains only the unique rows from this DataFrame.
Now, you can create a UDF in order to transform each record.
For example:
val df = sc.parallelize(Array((1, 2), (3, 4), (1, 6))).toDF("age", "salary")
// I obtain all different values. If you show you must see only {1, 3}
val distinctValuesDF = df.select(df("age")).distinct
// Define your udf. In this case a simple function is defined, but here things may get complicated.
val myTransformationUDF = udf(value => value / 10)
// Run that transformation "over" your DataFrame
val afterTransformationDF = distinctValuesDF.select(myTransformationUDF(col("age")))