For changing the number of decimals in percentage label, Follow the below steps :
Step 1 - Once you plot the bar graph or histogram, just right click on the measure that you used in bar chart visualization. Select Format from there, you will see a new window appears in left.
Step 2 - Axis and Pane columns will appear select Pane, then select Numbers and then Percentage.
Step 3 - Now you can select how many decimals you want.
To learn more about formatting in a Tableau visualizations check it tableau tutorial.