You are getting this error because you are calling the DataFrame constructor with invalid arguments. To create a data frame you need to pass data in a valid format. In your case you need to pass a dictionary with key as a string with value Email and value as a list of strings that represent email addresses. For example.:
email_dataframe = pd.DataFrame({ 'Email': ['[email protected]'] })
print(email_dataframe)
To learn more about different ways of using pandas, you can watch this video: