Yes, companies do hire for fresher with AWS Solution Architect Associate Certified. Anyone who is AWS certified as a Solutions Architect could apply for the job, it matters only that you possess the required skillset. The main role of AWS cloud support associate is to make migration of infrastructure and application into the cloud easier and provide expert solutions and techniques to troubleshoot their issues to enhance support systems for AWS customers.
If you are wishing to get AWS Certified Solutions Architect, then you must check out the AWS certification course from Intellipaat which offers several guided projects along with video courses to help you develop clarity in your concepts.
And in case if you are starting out as a novice, I would suggest you watch our YouTube video on AWS Associate Certification from our subject-matter experts.